Russian Mineralogical Society
XII General Meeting of the Russian Mineralogical Society
Synthesis and crystal structure of a new uranyl sulfate (C3H8N6)[(UO2)2(SO4)3(H2O)](H2O)

RMS-DPI code:  2015-1-103-0
Scientific session:  5. Mineralogical crystallography, crystal chemistry and new minerals (Fyodorov Session)
Author listing:  Gurzhiy V.V., Tyumentseva O.S., Krivovichev S.V.
Principal author:  Gurzhiy Vladislav Vladimirovich
Language:  Russian
Abstract - Summary 
(short description):
Single crystals of (C3H8N6)[(UO2)2(SO4)3(H2O)](H2O) were obtained by evaporation from aqueous solution at room temperature conditions. Novel compound crystalizes in monoclinic system [S.G. P21/n, a = 11.1194(4) Å, b = 10.5921(3) Å, c = 17.0143(6) Å, b = 101.405(2) o, V = 1964.34(11) Å3, Z = 4, R1 = 0.024]. Structure is based on the [(UO2)2(SO4)3(H2O)]2 layers, built up with corner shared uranium and selenium coordination polyhedra. Negative charge of the inorganic layers is compensated by protonated melamine molecules (C3H8N6)2+.
 
Date of presentation:  15/10/2015
Presentation Place:  Mining University, foyer of the Assembly Hall
 
RMS-DPI code:  2015-1-103-0
File of proceedings 
(PDF): 
 143 K
Status:  printed
Accepted:  03/09/2015
Contact author(s):  Gurzhiy, Vladislav Vladimirovich

Copyright © Russian Mineralogical Society, 1995-2011. All rights reserved.
http://www.minsoc.ru
printed on 20/09/2020