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200th Anniversary Meeting of the Russian Mineralogical Society
Saint Petersburg, Russia
10-13 October 2017
2017minsoc.ru
http://www.minsoc.ru/2017/
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Conferences & Meetings 200th Anniversary Meeting of the Russian Mineralogical Society
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Potassium-substituted clinoptilolite and its structural evolution under high pressure

RMS-DPI code:  2017-1-66-0
Scientific session:  2. Mineralogical crystallography and crystal chemistry.
Author listing:  Seryotkin Yu.V., Bakakin V.V.
Principal author:  Bakakin Vladimir Vasilievich
Language:  Russian
Abstract - Summary 
(short description):
The K-exchanged clinoptilolite has been studied by the single-crystal X-ray diffraction method under compression up to 4 GPa in penetrating (water-containing) and nonpenetrating (paraffin) media. The compression of the K-exchanged clinoptilolite in the 1:1 water/ethanol mixture results in the additional hydration because of entering 2.2 extra water molecules in the initial stage. Two more molecules are added under the further compression through the repopulation of partially vacant water positions. The additional hydration leaves the cation environment unchanged. When pressing in paraffin, the changes in the coordination cation polyhedra come to the slight decrease of the bond lengths. Variations in the hydration degree of the K-form under compression in penetrating and nonpenetrating media are exhibited by compressibility features of the compound

Zeolite, K-exchanged clinoptilolite, crystal structure, high pressure
 
RMS-DPI code:  2017-1-66-0
Pages:  118-119
File of proceedings 
(PDF): 
 149 K
Status:  printed
Accepted:  15/09/2017
Published on-line:  06/12/2017
Permanent address of publication:  http://www.minsoc.ru/2017-1-66-0/
Contact author(s):  Bakakin, Vladimir Vasilievich
 

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