The formation of perovskite in olivine-clinopyroxenite melanephelinites controlled by the lack of SiO2 in the initial melt at elevated concentrations it CA and Ti. In peridotite perovskite is formed by the interaction of early minerals from melilite and jacupiranga melt enriched with calcium. In Golinska carbonatite massif from the earliest series of rocks (ultramafic, militaryt-urtite, and turayevo) to the later series of the chemical composition of perovskite evolved in two major trends: in the calcite and dolomite carbonatites in luisitou (the enrichment of sodium and niobium); phoscorite Ц loparite (the enrichment of sodium and rare earth elements). Distribution spectra of rare earth elements in perovskite are characterized by a steep slope from light to heavy REE. Compared to Apatite, perovskite enriched in the light lanthanides and depleted in heavy.