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RMS Annual Session combined with the Fedorov Session 2012
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Presentations
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The first vanadate-carbonate K2Mn3[VO4]2(CO3): hydrothermal synthesis, crystal structure, comparative crystal chemistry

RMS-DPI code:  2012-1-188-0
Scientific session:  F1. Mineralogical crystallogrpaphy and crystal chemistry
Author listing:  Iakovleva E., Yakubovich O.V., Dimitrova O.V.
Principal author:  Yakovleva Ekaterina
Language:  Russian
Abstract - Summary 
(short description):
A new compound was obtained by hydrothermal synthesis in the system MnCl2 ľ V2O5 ľ K2CO3 ľ H2O (Ď = 280Đ, đ = 100 bar).
The unit cell parameters were determined on an Xcalibur-S diffractometer equipped with a CCD detector and MoK radiation (graphite monochromator): a = 5.201(1), ˝ = 22.406(3) Å, sp.gr. P63/m, Z = 2, dcalc. = 3.371 g/cm3, R1 (for all reflections with I > 4σ(I), 530) = 0.0222, ωR2 (for all reflections, 535) = 0.0563, parameters = 33.
The work examines ˝omparative ˝rystal ˝hemistry of the first vanadate-carbonate K2Mn3[VO4]2(CO3) and other synthetic compounds and minerals as members of a polysomatic series based on gibbsite-like octahedral layers linked with tetrahedra.
 
Date of presentation:  10/10/2012
Presentation Place:  Mining University, foyer of the Assembly Hall
 
RMS-DPI code:  2012-1-188-0
Proceeedings volume 
in the RMS catalogue:
 
Mineralogy in Ó whole space of the word.
File of proceedings 
(PDF): 
 259 K
Status:  printed
Accepted:  29/08/2012
Published on-line:  28/10/2012
Permanent address of publication:  http://www.minsoc.ru/2012-1-188-0/
Contact author(s):  Iakovleva, Ekaterina
 

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