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RMS Annual Session combined with the Fedorov Session 2012
Saint Petersburg, Russia
8-10 October 2012
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Calorimetric data for aromatic amines functionalization into NH2[ZN2-XCUXCOX (PO4)(HPO4)] (X=0.6) at the solid/liquid interface

RMS-DPI code:  2012-1-160-1
Scientific session:  F1. Mineralogical crystallogrpaphy and crystal chemistry
Author listing:  Lima Guerra D., Mello I.
Principal author:  Lima Guerra Denis
Language:  English
Abstract - Summary 
(short description):
The present investigation reports calorimetric determinations involving the functionalization of NH2[Zn2-xCuxCox(PO4)(HPO4)] (x=0.6) (CCZ-PH) with aromatic amines pyridine and -, -, and -picolines, by using the batch method in 1,2-dichloroethane, in order to study the energetic thermal effects of functionalization. The spontaneity of these systems, reflected in the negative Gibbs free energies and the favorable positive entropic values, agrees with the displacement of coordinated solvent molecules as the functionalization takes place. The functionalized matrices were named as CCZ-PH PY, CCZ-PH -PIC, CCZ-PH -PIC, and CCZ-PH -PIC.
 
Date of presentation:  10/10/2012
Presentation Place:  Mining University, foyer of the Assembly Hall
 
RMS-DPI code:  2012-1-160-1
Proceeedings volume 
in the RMS catalogue:
 
Mineralogy in а whole space of the word.
File of proceedings 
(PDF): 
 247 K
Status:  printed
Accepted:  29/08/2012
Published on-line:  05/11/2012
Permanent address of publication:  http://www.minsoc.ru/2012-1-160-1/
Contact author(s):  Lima Guerra, Denis
 

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